PSCM is under the hood, no point in using that for power at the steering wheel.
The Horn switch goes to C218B-10 (Ground) and C218B-9 (BCM). I'm not sure the current, or even the voltage from the BCM for it to detect that the switch is closed to ground. I'm not sure I would use that for +12V, for ground, yes it should be a great place for ground if tapped in between ground and switch.
The most I can be sure of the circuit path of the horn switch is:
Ground (G201) -- wire (GD133/BK) -- C226B-4 -- SASM -- C218B-10 -- wire (GN) -- C260-2 -- wire (BK) -- C217B-1 -- Horn Switch -- C217A-1 -- wire (RD) -- C260-1 -- wire (VT) -- C218B-9 -- SASM -- C226B-3 -- wire (CRH01/BU-WH) -- C2280C-50 -- BCM
(edit) it is very possible that in the BCM that wire is more or less a direct connection to the ground side of the relay in the Battery Junction Box (BJB) that controls the horns. Perhaps the BCM has a relay in there as a parallel ground source for the horn relay if the alarm is sounding.
If you look at that diagram you have for the C218B you'll see several unused pins, look at the clockspring unit and see if any of those pins exist there, maybe you can use a continuity tester with with a loose clockspring to find any pins on the other side that may also be unused.
I can't directly share any images of the manuals I have, I can share the links to where I bought them though.
2016 Wiring Diagram and
2017 Service Manual (I bought the 2017 CD because I could not find the 2016 one for the RS)